The cerium(IV)-alcohol couple in an acidic medium is an example of a redox system capable of initiating free radical polymerization. When the alcohol has a polymeric nature, the outcome of such a process is a block copolymer, a member of a class of compounds possessing many useful properties. The most common polymer with a terminal -OH group is poly(ethylene glycol) (PEG); however, the detailed...

An investigation into the chemiluminescence of fourteen organic acids and tris(2,2'-bipyridyl)ruthenium(II) was undertaken. Particular emphasis was placed upon the method of production of the reagent, tris(2,2'-bipyridyl)ruthenium(III), with cerium(IV) sulfate, potassium permanganate, lead dioxide and electrochemical generation. Analytically useful chemiluminescence was observed when Ce(IV) or ...

N-p-Chlorophenylcinnamohydroxamic acid reacts with cerium(IV) to form an orange coloured complex, quantitatively extractable into chloroform from alkaline medium. On the basis of this sensitive colour reaction, a new method for the extraction and spectrophotometric determination of cerium(IV) has been developed. The effects of foreign ions and sever al experimental variables on the extraction a...

A simple and sensitive spectrofluorimetric method was developed for the determination of biotin in pure form and in pharmaceutical preparations. The proposed method is based on the oxidation of the drug with cerium (IV) ammonium sulfate in acidic medium. The fluorescence of the produced Cerium (III) was measured at 365 nm after excitation at 255 nm. The different experimental parameters affecti...

The interactions between surface sulfate and surface vanadate species present on sulfated supported vanadia catalysts under dehydrated conditions have been investigated with infrared and Raman spectroscopies. The surface sulfate species present on sulfated TiO2, ZrO2, and Al2O3 supports and V2O5/TiO2, V2O5/ZrO2, and V2O5/Al2O3 catalysts have identical molecular structures, i.e., (M-O)3SdO, wher...

A simple, rapid and sensitive spectrophotometric method has been proposed for the determination of cerium(IV) using a phenothiazine derivative, propionyl promazine phosphate (PPP). This method is based on the formation of a red-colored radical cation upon a reaction of PPP with cerium(IV) in a phosphoric acid medium having maximum absorbance at 513 nm. Beer's law is valid over the concentration...

A simple and highly sensitive method is proposed for determination of trace amount of cerium. New method involves bleaching of greenish colour dye-malachite green, by the action of iodine, which is released by reaction between potassium iodide and cerium (IV) in acidic medium. Beer’s law is obeyed over concentration range of 0.6 to 4.6 μg cerium (IV) in final volume of 25 ml (0.024-0.184 ppm). ...

In this study a giant reagent such as Ce (SO4 )2 was used for removing different initial dye concentration (10-1000 mg/l) of reactive red 31 (R.R31) less than two minutes in a laboratory scale whereas the percent of dye removal efficiency was %99.9. The Langmuir, Freundlich and Tempkin adsorption models were applied to describe the equilibrium isotherms. The Langmuir model agreed very well with...